THE POLYMER SOCIETY OF KOREA

연구논문 초록집

초록 검색

세션명 미래소재: 태양광 에너지 활용 소재 기술
발표장 제5회장
논문코드 1L5-1
발표일 2021-10-21
발표시간 14:00-14:25
논문제목 Ternary Organic Solar Cells Based on a Wide-Bandgap Polymer with Enhanced Power Conversion Efficiency Over 17%
발표자 진성호
발표자 소속 부산대학교
저자 진성호, 타바마니 구굴라한트
소속 부산대학교
논문초록 A ternary strategy has been demonstrated as a promising method to further improve the performance of organic solar cells (OSCs). Herein, an efficient polymer SiCl-BDT was incorporated into a host binary PM7:Y7 system to fabricate ternary OSCs. SiCl-BDT possesses good complementary absorption and good compatibility with PM7. Also, the lowest unoccupied molecular orbital (LUMO) cascade energy level of SiCl-BDT is slightly lower than that of PM7, which enables efficient exciton generation and charge transfer in ternary OSCs compared with that of PM7:Y7, leading to higher efficiency. The optimized ternary devices with 15 wt% SiCl-BDT in the donors achieve a PCE of 17.09%. Besides, we found that the photovoltaic device performance of ternary OSCs can be further established to an impressive efficiency of 17.40% by employing a highly effective interface strategy. Thus, our newly advanced method guarantees highly efficient and stable ternary OSCs.